This is the task list I wrote to get competent NT admins quickly up to speed on Solaris. It's not directly relevant to Linux and so on, or, indeed, many of your lives. But I prepared it for posting for zey, so thought I might as well make an entry of it. The idea is to start them on the PFY stuff and show them where the good stuff is.
Your suggestions are welcomed. It needs better stuff, rather than more - the list is too long already. (The hardest part is teaching them to learn from those squiggles on a page or command line, rather than bright shiny pictures, ticky boxes and clicky buttons on a screen.) Generalised equivalents of the above, too.
And if they're not competent, the list above is sufficiently eminently reasonable that it'll be readily apparent to your mutual boss in short order.
Edit: Please, less vi flamewar and more useful NT admin herding tips!